Life cycle assessment of HFC-134a production by calcium carbide acetylene route in China

HFC-134a is a widely used environment-friendly refrigerant. At present, China is the largest producer of HFC-134a in the world. The production of HFC-134a in China mainly adopts the calcium carbide acetylene route. However, the production route has high resource and energy consumption and large waste emission, and few of the studies addressed on the environmental performance of its production process. This study quantified the environmental performance of HFC-134a production by calcium carbide route via carrying out a life cycle assessment (LCA) using the CML 2001 method. And uncertainty analysis by Monte-Carlo simulation was also carried out. The results showed that electricity had the most impact on the environment, followed by steam, hydrogen fluoride and chlorine, and the impact of direct CO₂ emissions in calcium carbide production stage on the global warming effect also could not be ignored. Therefore, the clean energy (e.g., wind, solar, biomass, and natural gas) was used to replace coal-based electricity and coal-fired steam in this study, showing considerable environmental benefits. At the same time, the use of advanced production technologies could also improve environmental benefits, and the environmental impact of the global warming category could be reduced by 4.1% via using CO₂ capture and purification technology. The Chinese database of HFC-134a production established in this study provides convenience for the relevant study of scholars. For the production of HFC-134a, this study helps to better identify the specific environmental hotspots and proposes useful ways to improve the environmental benefits.     

Integrated LaB6/g-C3N4 solar absorber for solving dye accumulation during solar steam generation

Solar steam generation has attracted considerable interest due to its easy accessibility and sustainability. However, dye molecules were gradually concentrated on bulk water or the surface of solar absorbers during the disposal of dye wastewater. Herein, LaB₆/g-C₃N₄ composites were immobilized on porous cotton cloth, served as a solar absorber resistant to dye clogging. The optimal solar absorber possessed solar harvesting of 92.3% and showed great application potential in the field of the treatment of dye wastewater. This study presented a new approach for the treatment of dye wastewater.     

王家岭选煤厂输送系统提能改造研究

针对当前王家岭选煤厂日均全粒级处理能力远低于矿井提能后的处理能力的问题,对输送系统的提能改造方案进行分析研究,对选煤厂生产能力进行改造.生产实践表明,通过改造后,输送能力完全满足选煤厂10.00 Mt/a的处理能力,同时降低了输送系统设备故障率及维护成本,改造效益显著.     

Phase composition,microstructure and thermophysical properties of the Srx(Zr0.9Y0.05Yb0.05)O1.95+x ceramics

Sr_x(Zr_0.9Y_0.05Yb_0.05)O_1.95+x (x=1.0, 0.9, 0.8, 0.7) ceramics were prepared by solid state reaction sintering. The sintered Sr_1.0(Zr_0.9Y_0.05Yb_0.05)O_2.95 is a single-phase solid solution while the sintered Sr_x(Zr_0.9Y_0.05Yb_0.05)O_1.95+x (x=0.9?0.7) are composites, and a significant grain growth inhibition is observed in the sintered Sr_x(Zr_0.9Y_0.05Yb_0.05)O_1.95+x (x=1.0, 0.9). Rare-earth elements distribution in the bulk materials indicates that Yb and Y preferentially substitute Zr-sites in SrZrO₃, and the highest solubility of RE₂O₃ in pure SrZrO₃ is ～0.8 mol%. The sintered Sr_x(Zr_0.9Y_0.05Yb_0.05)O_1.95+x have high thermal expansion coefficients up to ～11.0×10^?6 K^-1 (1200°C). Sr_0.8(Zr_0.9Y_0.05Yb_0.05)O_2.75 has the lowest thermal conductivity of 1.38 W·m^-1·K^-1 at 800°C. Sr_x(Zr_0.9Y_0.05Yb_0.05)O_1.95+x (x=1.0, 0.9, 0.8) show no phase transition from 600 to 1400°C, whereas Sr_x(Zr_0.9Y_0.05Yb_0.05)O_1.95+x (x=0.9, 0.8) have excellent high-temperature phase stability over the whole investigated temperature range. Therefore, Sr_x(Zr_0.9Y_0.05Yb_0.05)O_1.95+x (x=1.0, 0.9, 0.8) are considered as promising TBCs materials that might be operated at higher temperatures compared to YSZ.     

原料煤低位发热量变化对气化运行成本的影响

通过列举原料煤低位发热量变化后煤耗增加及相关部分的影响,对变化前后运行成本进行对比分析,得出结论:当原料煤单价为每吨353元时,低位发热量每降低418kJ/kg,气化装置运行成本增加约20元。